chelates

Translated by Google

There is certain amount of micronutrients in waterc that plants can uptake by roots and leafs for health grow. Some of elements , especially speeking of iron (Fe ), which don't last long in water as free cationt, and thanks very common phenomena, such elements get forms which are not no longer soluble as insoluble crystals which most likely will be unavailable to the plant. Adding these forms micronutrients to water is therefore inappropriate. I have to mention that some elements are toxic to fishes and invertebrates copper, zinc, cobalt ...). Fortunately, there are substances , called chelates , which can micronutrients keep in soluble form for a long time.

The name "chelate" comes from the Greek "chela" - "crab claw" . Chelators or chelating agents are ligands capable to form a molecular ring ( rings see picture below) with metal ions. Rings of such ligand "protects" the metal atom from creation of strong ties and the transition to water-insoluble forms not accessible to the palnts - for example Fe 3+ . Chelates generally have excellent solubility in water.
Basically metals (not all ) are available in the aquarium (problematic is mainly iron) only after some time ( dependent on many factors like pH , protein content hardness of the water ... ) and then transite to a state where they are poorly accessible for plants and for some species of plants are not accessible at all. Chelate is a large molecule that "wrapps and hold" metal atom and protect it from reacting with other ions. This will also prevent the toxicity of heavy metals such as zinc and copper.

Chelators are not used only as a fertilizers. You may meet it in the food industry , where maintaining the taste of food (from beer to sauces at McDonalds) . In medicine, they are used for curing of heavy metals poisoning - chelate is dissolved in blood and then easily filtered out by liver or kidneys. Another important use is in chemistry.


Figure 1 : chelate (circles ) wrapping (protecting ) metal ( yellow )


Figure 2: The model EDTA

Plants require metals for proper growth. These metals are received from surrounding of the plants in the chelated forms. Plants can produce acids themselves with similar effects as chelate agents(eg citric acid) and only used to dissolve the metal and its transport to the plant body. Already chelated elements are easily accessible for the plant. Proccess of releasing of metal from chelate is not known.

Stability of chelates

Stability of chelates is quite complicated. Each chelate "holds" (is stable) only under certain conditions.
  • radiation
  • The problem of all of the large molecules, which include chelates, is sensitivity to radiation of high frequency (energy) - UV light is a good example . UV light can destroy chelate as well as is able to damage your DNA and cause cancer.

    Figure 3 : Stability of Fe -DTPA and its temperature and lighting dependency

  • pH
  • Each chelate is stable only in a certain pH range, depending on which chelating agent has been used.

  • competition
  • Figure 4 shows the stability of chelates in clean water. The problem is if the solution is other metals (calcium and magnesium are also metals!) , Unbound chelated , in part , depends on the concentration of the winner of the iron and iron chelate displaced. If there are other metals (not bounded in chelate) ions (from sulfates or chlorides) in solution, they can displace original bounded metal in chalate.It shows Figure 5 Stir the micro elements in PMDD or Estimative Index always separately!

Figure 4: stability of chelates
red = unstable, blue = stable
Figure 4: stability of chelates red = unstable, blue = stable


figure 5 Substitution of Fe in Fe-DTPA by free metals

From the tables of stability can be inferred suitability of chelated mixtures of micronutrients:

  • Canadian Plantex CSM+B (only Fe-EDTA)is suitability for water up to pH 6,5
  • Dutch Tenso coctail (Fe EDTA+DTPA)is suitability for water up to pH 7,5
  • Czech MicroMix plus (FeEDTA, DTPA, EDDHMA, gluconate)is suitability for water up to pH 9
However, when daily dosed all "irons" can be used. Stabilty chelate is determined by the size and the quantity of circles of ligand. Effect of chelatation is strongest if the circles "protecting" metal are formed of 5 or 6 atoms.

The most commonly used chelating agents are :
  • EDTA - ethylenediaminetetraacetic acid
  • DTPA - diethylene triamine pentaacetic acid
  • EDDHA - ethylendiamindihydroxyphenylacetic acid
  • EDDHMA -
  • EDDHSA - ethylendiaminedisulfohydroxyphenylacetic acid

                 
  
  

  
Fe - EDDHMA    Fe -DTPA Fe -EDTA   


EDDHA , EDDHMA and EDDHSA chealtes only iron. EDTA and DTPA chelates iron and copper, zinc, manganese. Iron ( Fe 2 + also Fe 3 + ) . EDTA and DTPA are not very stable at high pH (see figure). Because Fe EDDHMA is much more stable in alkaline environment and should therefore be preferred over FeEDTA and FeDTPA waters with a high content of calcium carbonate . Fe - EDDHA is of 2.5 x expensive than EDTA. Its use is very effective and usually just part does the same effect effect in comparison with Fe - EDTA. Fe - EDTA is the least stable . EDTA is often used because it is inexpensive. There is known effect of Fe- EDTA and Fe -DTPA mixture where resultant mixture is as stable as Fe -DTPA itself .
The bond strength Fe - EDDHA is 100 billion times stronger than the Fe - DTPA , and that is 1000 times stronger than Fe - EDTA.


If you decide to buy chelates in your store be careful what you are buying, because there is more then 5 different compound sold as "Fe EDTA". Some of them contain amonia which your fish might not fully appreciate. So if you do not know what you are doing, do not do it.
Next complication when buying chelate like EDDHMA are isomers. Isomers are compounds with the same chemical formula but have different physically 3D arrangment. It also gives them different properties. When producing EDDHMA - Fe always look at ortho and para isomers ration. While the ortho isomer has excellent properties, phara izomer is is not considered as a chelate. Fe-Eddhma 6% , in fact, usually contains only 70% of chelated iron (4.8%) Links :
3D EDTA

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#204 
QuickBooks Error 618

Quite possibly, even after checking out all of the above fixes you might nevertheless be stuck with QuickBooks error 6189. This kind of a scenario, avoid any longer wastage of valuable time and prevent more hit and trial fixes or perhaps you could cause further damage.

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#203 
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#202 
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#200 
HP printer technical

 

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#199 
QuickBooks Error 618

Incorrect or unfinished installing of QuickBooks may also end up in incorrect entries into the Windows registry causing this error. A Malware or virus attack in Windows framework resulting in corruption of QuickBooks program files when you look at the system triggers this error.

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#198 
QuickBooks POS Suppo

We are the top-notch tech support team for QuickBooks errors because our executives move heaven and earth to meet our customers.We are available 24*7 at your service because we understand very well that problems usually do not come with any prior notice.

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#197 
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Your accounting and financial activities may get affected as a result of QuickBooks error 3371. The error code show through to your personal computer screen as numbers or number letter combinations that correspond into the particular error or variety of error occurring.

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#196 
MIO MAPS UPDATE

 

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#195 
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#194 
Incredimail Support

Very informative article. This article made me add something new to my knowledge. Thanks. Keep up the good work. visit INCREDIMAIL SUPPORT NUMBER for email related features. IncrediMail customer service is an email customer program for supplanting your normal email program however, it likewise works with Web-based email records, for example, Hotmail and Yahoo Mail. http://www.supportincredimail.com/" target="_blank">http://www.supportincredimail.com/

 

#193 
QuickBooks Payroll

QuickBooks Enterprise Support telephone number  is assisted by a bunch this is certainly totally dependable. It truly is a well liked proven fact that QuickBooks has taken about plenty of improvement in the field of accounting. As time passes amount of users and selection of companies that can be chosen by some one or perhaps the other, QuickBooks Enterprise has got lots of selections for a lot of us.

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#192 
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#191 
HP Laserjet Error Co

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#190 
QuickBooks Error 152

Another program is running simultaneously. Corrupted windows registry is there from a current installation or uninstallation of QB related software. You can talk to a technical expert at QuickBooks support number for instant troubleshooting of QuickBooks Error 15227.

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#189 
QuickBooks Payroll T

It uses Automatic tax calculation to generate paychecks. You need to utilize it to make paychecks and hand it as much as your workers Direct deposit: it is possible to directly deposit the payroll with this employees making use of their savings bank accounts.

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#188 
Intuit QuickBooks Su

Every business wishes to obtain revenues all the time. But, not every one of you'll be capable. Do you realize why? It really is because of not enough support service. You will end up not used to the business enterprise and then make lots of errors. You yourself don’t find out how much errors you are making. When this occurs it is actually natural to obtain a loss in operation. 

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#187 
QuickBooks POS Suppo

Also, sometimes you may face problem in updating your software aided by the latest updates to keep it as much as date aided by the latest functionalities.

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#186 
QuickBooks Enterpris

 In May 2002 Intuit thrown QuickBooks Enterprise Solutions for medium-sized businesses. https://www.helplinephonenumber.com/quickbooks-enterprise-support-number/">QuickBooks Enterprise Support Number  here to make tech support team to users. In September 2005, QuickBooks acquired 74% share related to market in the united states.

#185 
Amanda miller

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#184 
QuickBooks Enterpris

The most time-consuming business type is retail. It needs large amount of some time hard work. With QB Enterprise it becomes very easy to control the complete hassle regarding the selection of business.

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#183 
HP Printer Helpline

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#182 
HP Printer Customer

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#181 
HP Printer Support P

Drift mode is a different sort of kind of mode which increases the print speed. But there is a demerit of using drift mode; you can’t take a good print using this mode. This mode uses a tremendously little quantity of ink which reduces the ink usage. However if you need to take bright and colorful prints you then need certainly to switch back again to normal mode from the drift mode. You can easily toggle the mode from the settings.

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#180 
Scarlett ward

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#179 
QuickBooks Enterpris

By 2000, Intuit had industrialized Basic and Pro versions concerning the software and, in 2003, underway offering industry-specific versions, with workflow procedures and reports intended for all those business types along with terminology linked to the trades.

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#178 
QuickBooks Error 152

Suggested: with a particular end goal to repair your framework and Quickbooks Update Error 15217, download and utilize the Reimage underneath. Although installation and payroll update download not hard task, but in any case 15217 occurred, call QuickBooks Support Number for guidance to fix .

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#177 
QuickBooks POS Suppo

The QuickBooks POS Support Number   has a feature that would maintain all the users stocks with every deal on the way. The module for stock stores cost details, division, depiction, measurements, shading, deals, values, status, seller information, buyer information, reorder points, ALU, and UPC. In case of confusion or issues, the QuickBooks Point of Sales Support phone numbercan be used to contact the expert panel at the QuickBooks customer service.

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#176 
QuickBooks Enterpris

QuickBooks Enterprise Number USA  team can help you cope with all of the issues of QB Enterprise. Now let’s take a look from the industry versions so that it has furnished us with. You will find six types of industry versions that QB Enterprise offers.

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#175 
QuickBooks Tech Supp

The principal functionality of QuickBooks is dependent upon company file. On the basis of the experts, if you would like solve the problem, then you'll definitely definitely need certainly to accept it first.

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#173 
QuickBooks Payroll S

Intuit QuickBooks payroll accounting software allows you to ready your invoices, manage your web business payrolls, track your business inventory, control cash flow, and be tax-ready. Intuit Online Payroll could be the better option for companies looking towards automating their accounting solutions and take their company to new heights.

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#172 
QuickBook Tech Suppo

The key intent behind https://www.getenterprisesupport.com/quickbooks-help-support-phone-number/">QuickBooks Tech Support Phone Number is to offer the technical help 24*7 so as with order to prevent wasting your productivity hours. This will be completely a toll-free QuickBooks client Service variety that you won’t pay any call charges.

#171 
Quickbooks payroll C

The software holds some of the really important files for your company and business and so it becomes essential that you create a backup of each and every data that is created. So that if by chance, the original gets corrupted or deleted, you have a backup source available with you. If you are not able to understand how it can be done, then it is suggested that you take the assistance from https://www.qbaccounting-support.com/quickbooks-payroll-support/">Quickbooks payroll Support and do the needful.

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#170 
QuickBooks Payroll S

Our hard-working team that contributes within the over all functioning of the business by fixing the errors that may pop up in QuickBooks Payroll saves you against engaging in any problem further.We have a team that is extremely supportive and customer friendly.Our customer care executives at Quickbooks Payroll Support Phone Number  do not hesitate from putting extra efforts to give you rest from the troubles due to QB Payroll errors.

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#169 
QuickBooks Support P

To verify internet and private firewall setting-

 

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#168 
QuickBooks Payroll T

Having employees in your online business also signifies the growth of one's business, that will be considered essential by many business people. Thus, when you have employees in your organization, another component that becomes equally essential is the employees’ payroll https://www.freepostclassified.xyz/post-3887/QuickBooks-Payroll-Support-Phone-Number.html">QuickBooks Payroll Tech Support Number If you are hiring an employee be effective for your business, it's also important to pay for wages to them. In the event that business which you own has a whole lot many employees, all of them being given a certain task, then you'll definitely need something more than just a mere book of accounts.

#167 
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The QuickBooks Error 15223 can happen when any relevant windows file is damaged or has any error. The windows files may be damaged because of the various reasons and it also causes this error.

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#166 
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For such variety of information, be always in touch with us through our blogs. Searching for the reliable way to obtain assist to create customer checklist in QB desktop, QuickBooks online and intuit online payroll? Our QuickBooks Payroll Support service will help you better.

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#165 
QuickBooks Error 152

QuickBooks is mainly configured to the office through internet explorer. In fact, Intuit encourages the application of Internet Explorer for making use of QuickBooks. So, if Internet Explorer is not the default browser, its use of the network could easily get interrupted.

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#164 
QuickBooks Error Cod

Basic, Standard or Enhanced Payroll: Choose Employees > My Payroll Service > Account/Billing Information or Account Info/Preferences. Log into the Intuit Account to see the QuickBooks Payroll Account Maintenance page and verify your subscription is Active.

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#163 
QuickBooks Enterpris

QuickBooks Enterprise has its own awesome features which will make it more reliable and efficient. Let’s see some awesome features which could have caused that it is so popular. If you are also a QuickBooks user and wants to find out more concerning this software you may turn to the QuickBooks Enterprise customer service number.

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#162 
QuickBooks Support P

A small grouping of execs can handle you manually as a result of they’re absolute to offer the standard services. So, in the event that you face any issue along with your package you don’t need to go anywhere except us. You just need certainly to build a straightforward charge less call on our QuickBooks Support variety and rest leave on united states country. No doubt, here you'll find the unmatchable services by our supportive technical workers.

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#161 
QuickBooks Payroll S

QuickBooks is an accounting software package generated by Intuit. In QuickBooks, makes it possible to all of the billing, bookkeeping, and invoicing at one place.

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#160 
QuickBooks Payroll S

Since outsourcing is very a costly affair, this is why the explanation for an alternative emerged. When this occurs, a far better choice is payroll support with accounting software like QuickBooks that assimilates the processing of payroll as a part of the program. QuickBooks Payroll Support is a renowned accounting software on the market which comes along the payroll process ensuring all of the financial and tax related activities of this business are completed effortlessly.

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#159 
QuickBooks Customer

Our support also extends to those errors when QB Premier is infected by a virus or a spyware. We also handle virtually any technical & functional issue faced during installation of drivers for QuickBooks Premier Version. We also troubleshoot any kind of error which can be encountered in this version or this version in a multi-user mode.

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#158 
QuickBooks Customer

Our support also extends to those errors when QB Premier is infected by a virus or a spyware. We also handle virtually any technical & functional issue faced during installation of drivers for QuickBooks Premier Version. We also troubleshoot any kind of error which can be encountered in this version or this version in a multi-user mode.

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#157 
QuickBooks Update Er

In the event that error can there be, then do on a clean Uninstall/Reinstall within the ‘Selective startup.’ Ensure to manually rename- C:\program files\common files\intuit\QuickBooks.

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#156 
QuickBooks Payroll S

The computer setting with respect to date and time may not be correct.The authentication code filled in at the time of updating a Point of Sales Desktop copy may be wrong.

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#155 
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Dial the Quickbooks Tech Support Phone Number +1-888-833-0109 QuickBooks Bolster Telephone Number and get the help from the best in the business. We are offering help administrations 24×7   

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#154 
QuickBooks Error 152

QuickBooks Payroll allows you to definitely handle multiple Payroll chores without any complications. Paying your employees on time is regarded as an excellent business practice and any delay in payroll processing can negatively affect your company reputation. QuickBooks Error 15241 is a payroll error that occurs when a person tries to update payroll and Error message “You receive error 15241: The payroll update did not complete successfully” pops up on users computer screen.

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#153 
QuickBooks Error 618

We hope using the above fixes you will be able to solve QuickBooks error code 6189. Remember, if the manual fixes don’t work in most cases, you can always rely on an automated reliable solution like Stellar Repair for QuickBooks Software.

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#152 
QuickBooks Error 618

We hope using the above fixes you will be able to solve QuickBooks error code 6189. Remember, if the manual fixes don’t work in most cases, you can always rely on an automated reliable solution like Stellar Repair for QuickBooks Software.

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#151 
QuickBooks POS Tech

Enhanced Payroll and Full-service <a href="https://www.solveaccountingerror.com/quickbooks-point-of-sale-support/ ">QuickBooks POS Tech Support Number</a> are encompassed in Online Payroll whereas Basic, Enhanced and Assisted Payroll come under Payroll for Desktop.

 

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QuickBooks Support P

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#149 
QuickBooks tech Su

QuickBooks has availed many further versions with this particular software namely QuickBooks Pro, QuickBooks Premier, QuickBooks Enterprise, QuickBooks Point of Sale, QuickBooks Payroll, QuickBooks Accountant, QuickBooks Mac and QuickBooks Windows & we fix all Quickbooks tech issues. Amongst a majority of these versions you may possibly select the the one that suits your on line business the greatest. As you should really be realizing that QuickBooks has made bookkeeping an easy task, you will find occasions when you may face a few errors that will bog across the performance when it comes to business. QuickBooks Support telephone number is the better location to find instant help for almost any QuickBooks related trouble.

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#148 
QuickBooks Error 618

This QuickBooks Error 6189 816 error happens when opening a business file and certainly will be fixed if you restart your computer or laptop along with your server. Restart each computer which has usage of your company file.

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#147 
QuickBooks Error C34

QuickBooks Enterprise is a fantastic pick to suffice the elaborate and advanced needs related to businesses. QuickBooks Desktop is highly superior and technologically updated, however, sometimes the users might face some errors. [b][url=https://www.247supportphonenumber.com/quickbooks-error-code-c343/]QuickBooks Error 343[/url][/b] is just one more error that the users encounter.

#146 
QuickBooks Error 618

QuickBooks Error 6189 - How to Fix | : This QuickBooks Error 6189 816 error happens when opening a business file and certainly will be fixed if you restart your computer or laptop along with your server. Restart each computer which has usage of your company file.

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#145 
QuickBooks Error 152

QuickBooks error 15240 usually occurs because of Internet Explorer security settings or misconfiguration of Firewall settings. A common real cause to error 15240 is incorrect data & time settings in the system.

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#144 
QuickBooks Tech Supp

Although smaller businesses might not have any far-reaching purpose their foundation completely is determined by their capital base, ownership type, income  & expenditure level. Also, all smaller businesses have never their future growth determined as multinational or big small business ventures do.

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#143 
QuickBooks Tech Supp

Here comes the role of accounting software; as well as, the QuickBooks could be the one to rely on completely. https://www.helplinephonenumber.com/">QuickBooks Tech Support Number assists one to overcome all bugs associated with the enterprise types of the application form. Enterprise support team members remain available 24×7 your can purchase facility of best services.

#142 
uickBooks Tech Suppo

QuickBooks, a credit card applicatoin solution that'll be developed this kind of a way that one can manage payroll, inventory, sales and each other need of small businesses. Each QuickBooks software option would be developed centered on different industries and their demands to be able to seamlessly manage all your business finance whenever you want plus all at once. Do not need to worry if you're stuck with QuickBooks issue in midnight as our technical specialists at QuickBooks support cell phone number is present twenty-four hours just about every day to serve you combined with best optimal solution very quickly.

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#141 
QuickBooks Error (-1

QuickBooks Error code 12 0 often takes place when system settings are wrongly configured or irregularities when you look at the Windows registry. QuickBooks Error code 12 0 can easily be fixed with a particular software configured to solve common system registry issues.

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#140 
QuickBooks Pro Supp

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#139 
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#138 
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#135 
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#132 
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#120 
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#119 
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#118 
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#116 
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#114 
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#113 
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#112 
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#103 
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#5 
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Ahoj, velice zajímavý článek. Měl bych dotaz ke stabilitě vázané na světlo a teplotu. V grafu uvažuješ situace s vysokými teplotami 20 a 40°C. Mohl bys prosím přidat (nebo alespoň popsat) graf zohledňující stabilitu při skladování roztoku v lednici v neprůhledné lahvi? Tedy tma a teplota kolem 6-8 stupňů. Nepovedlo se mi ani v zahraničních zdrojích dopátrat zpracování této závislosti a i když předpokládám, že stabilita bude vyšší, je určitě velký rozdíl mezi 14 dny a třeba třemi měsíci... Díky. p.s. neškodilo by vymazat ten post níže od zyf.. :-/

#4 
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#3 
Tomáš Dobrý den, znamená to, že Tenso Coctail je lepší než Plantex, protože obsahuje DTPA-FE?
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Peter Dobrý text.